Gelatin aerogel with good mechanical properties and adjustable physical properties for boron adsorption from salt...

A composite aerogel with good mechanical properties and adjustable physical properties was synthesized by a sol-gel technique on the base of gelatin for the boron adsorption from water solution. The adsorption key variables, for instance, initial boron concentration (C₀) (900-1100 mg/L), the contact time (t) (8-9 h), and pH (9-11), were optimized using central composite design to obtain improved boron adsorption performance of epichlorohydrin-modified gelatin (EMG)/N-methyl-d-glutamine (NMDG) aerogel loaded with hydroxylated carbon nanotubes (EMG@NMDG). The adsorption followed the pseudo-second-order and Freundlich model. At pH of 10, C₀ of 1000 mg/L and t of 10 h, the largest adsorbed amount of EMG@NMDG was 85.79 mg/g. Regeneration experiments were carried out by eluting the adsorbent using HCl. The analysis showed that the adsorption in actual brine was 62.65 mg/g. Therefore, the developed EMG@NMDG aerogel has potential value for the boron extraction from brine and wastewater.