Permeable reactive composite approaching cathode enhanced Cr removal in soil using the byproduct of electrokinetic...

Cost-effective techniques with significant removal rates and low energy consumption are urgently required for in-situ Cr-contaminated soil remediation to reduce potential environmental toxicity to the ecosystem and human bodies. Electrokinetic technology is a valuable and promising soil remediation technology; however, the acidic and alkaline fronts evolution induced by the electrokinetic byproducts (H⁺, OH^-) has significant hindering characteristics for ion removal. To effectively utilize the byproducts for enhancing Cr elimination, this paper proposed the permeable reactive composite approaching cathode with rhamnolipid-modified biochar as reactive material. Power utilization efficiency (η) was presented to comprehensively evaluate the target species elimination effect, considering removal rate and energy consumption. Results suggested that biosurfactant rhamnolipid stimulated Cr removal in acid and base fronts. Acid front induced rhamnolipid protonation reducing anolyte Cr(VI) to Cr(III), and base front induced rhamnolipid deprotonation complexing with Cr(III) and expediting Cr(VI) dissolution by electrostatic repulsion. Permeable reactive composite approaching cathode induced the maximum removal rate of Cr(VI) and Cr(III) in each section by impelling the alkaline front. Approaching cathode caused increased resistance and energy consumption in the near-anode regions, ultimately decreasing energy utilization efficiency. Optimized moving frequency and applied potential magnitude could adjust power consumption distribution in a single soil layer to obtain better electrokinetic removal performance of contaminates. This work provided essential scientific and practical importance for in-situ electrokinetic remediation of Cr(VI) and Cr(III), considering elimination efficiency and energy consumption in the future.