Influence of Air Mass Source Regions on Signatures of Surface-Active Organic Molecules in Size Resolved Atmospheric...

The physical and chemical properties of atmospheric aerosol particles depend on their sources and lifetime in the atmosphere. In coastal regions, sources may include influences from marine, continental, anthropogenic, and natural emissions. In this study, particles in ten diameter-size ranges were collected, and particle number size distributions were measured, at Skidaway Island, GA in May and June 2018. Based on air mass back trajectories and concentrations of major ions in the particles, the air mass source regions were identified as Marine Influenced, Mixed, and Continental Influenced. Organic molecules were extracted from the particles using solid-phase extraction and characterized using tensiometry and high-resolution mass spectrometry. The presence of surfactants was confirmed in the extracts through the observation of significant surface tension depressions. The organic formulas contained high hydrogen-to-carbon (H/C) and low oxygen-to-carbon (O/C) ratios, similar to surfactants and lipid-like molecules. In the Marine Influenced particles, the fraction of formulas identified as surfactant-like was negatively correlated with minimum surface tensions; as the surfactant fraction increased, the surface tension decreased. Analyses of fatty acid compounds demonstrated that organic compounds extracted from the Marine Influenced particles had the highest carbon numbers (18), compared to those of the Mixed (15) and Continental Influenced (9) particles. This suggests that the fatty acids in the Continental Influenced particles may have been more aged in the atmosphere and undergone fragmentation. This is one of the first studies to measure the chemical and physical properties of surfactants in size-resolved particles from different air mass source regions.