ZIF-67 grafted-boehmite-PVA composite membranes with enhanced removal efficiency towards Cr(VI) from aqueous...

In this work, we developed a thin membrane of boehmite-polyvinyl alcohol composite (BOPOM) (diameter ∼ 5 cm) grafted ZIF-67 combing sol-gel and in-situ growth methods. The fabricated materials were characterized using FT-IR, SEM, XRD, TGA, XPS, and N₂ sorption techniques. Results indicate that ZIF-67 nanocrystals were well-grafted into the AlOOH-PVA matrix with reduced crystallite size. Furthermore, the decorated ZIF-67 offered additional porous structures and adsorption sites onto the membrane, enhancing their removal efficiency towards Cr⁶⁺ compared to the undecorated and pristine ZIF-67. At pH ∼5.5, the harvested ZIF-67/BOPOM exhibited the highest Cr⁶⁺ uptake capacity of ∼56.4 mg g^-1. Kinetic studies showed that the chromium adsorption on the prepared materials obeyed the pseudo-second-order model, and the kinetic parameters followed the order ZIFF-67/BOPOM (0.020 mg g^-1 min^-1) > BOPOM (0.011 mg g^-1 min^-1) > ZIF-67 (0.006 mg g^-1 min^-1). Notably, the adsorption mechanism study revealed that adsorbed Cr⁶⁺ was reduced to Cr³⁺, and the reduction yield was boosted owing to grafting ZIF-67 into the BOPOM. In addition, the fabricated ZIF-67/BOPOM can simultaneously remove Cr⁶⁺ and methyl orange dye (MO) in the solution due to their synergetic effects on each other. Furthermore, the hybrid membrane ZIF-67/BOPOM showed a chromium removal efficiency of ∼78.2% after four successive adsorption-desorption cycles. This study indicates that grafting nanocrystals ZIF-67 onto the super-platform boehmite-PVA is a promising strategy to harvest an adsorbent with a high adsorption ability, cost-effectiveness, and reduced secondary pollution risks.