Enhanced ferrate(VI) oxidation of organic pollutants through direct electron transfer

Fe(VI) is a versatile agent for water purification, and various strategies have been developed to improve its pollutant removal efficiency. Herein, it was found that in addition to intermediate iron species [Fe(IV)/Fe(V)], direct electron transfer (DET) played a significant role in the abatement of organic pollutants in Fe(VI)/carbon quantum dots (CQDs) system. Around 86, 83, 73, 64, 52, 45 and 17% of BPA, DCF, SMX, 4-CP, phenol, p-HBA, and IBP (6 μM) could be oxidized by 30 μM of Fe(VI), whereas with the addition of CQDs (4 mg/L), the oxidation ratio of these pollutants increased to 98, 99, 80, 88, 87, 66 and 57%, respectively. The negative impact induced by solution pH and background constituents on Fe(VI) abatement of pollutants could be alleviated by CQDs, and CQDs acted as catalysts for mediating DET from organic pollutants to Fe(VI). Theoretical calculation revealed that iron species [Fe(VI)/Fe(V)/Fe(IV)] was responsible for the oxidation of 36% of phenol, while DET contributed to the oxidation of 64% of phenol in the Fe(VI)/CQDs system. Compared with iron species oxidation, the CQDs mediated DET from pollutants to Fe(VI) was more efficient for utilizing the oxidation capacity of Fe(VI). The DET mechanism presented in the study provides a prospective strategy for improving the pollution control potential of Fe(VI).