Genetic programming-based predictive model for the Cr removal effect of in-situ electrokinetic remediation in...

Soil electrokinetic remediation is an emerging and efficient in-situ remediation technology for reducing environmental risks. Promoting the dissolution and migration of Cr in soil under the electric field is crucial to decrease soil toxicity and ecological influences. However, it is difficult to establish strong relationships between soil treatment and impact factors and to quantify their contributions. Machine learning can help establish pollutant migration models, but it is challenging to derive predictive formulas to improve remediation efficiency, describe the predictive model construction process, and reflect the importance of the predictors for better regulation. Therefore, this paper established a predictive model for the electrokinetic remediation of Cr-contaminated soil using genetic programming (GP) after determining the characteristic parameters which influenced the remediation effect, described the model's adaptive optimization process through the algorithm's function, and identified the sensitivity factors affecting the Cr removal effect. Results showed that the Cr(VI) and total Cr concentrations predicted by GP were in satisfactory agreement with the experimental values, 92% of the training data and 90% of the validation data achieved errors within 1%, and could fully reflect the target ions' content variation in different soil layers. By substituting the above prediction formulas into Sobol sensitivity analysis, it was determined that conductivity, pH, current, and moisture content dramatically affected the Cr content variation in distinguished regions. For overall contaminated area, the system current and soil pH were the most sensitive factors for Cr(VI) and total Cr contents. Remediation efforts throughout the contaminated area should focus on the role of current versus soil pH. GP and sensitivity analysis can provide decision support and operational guidance for in-situ soil electrokinetic treatment by establishing a remediation effect prediction model, expediting the development and innovation of electrokinetic technology.