Recent advances in removal of inorganic anions from water by chitosan-based composites: A comprehensive review

Chitosan is a modified natural carbohydrate polymer that has been found in the exoskeletons of crustaceans (e.g., lobsters, shrimps, krill, barnacles, crayfish, etc.), mollusks (octopus, oysters, squids, snails), algae (diatoms, brown algae, green algae), insects (silkworms, beetles, scorpions), and the cell walls of fungi (such as Ascomycetes, Basidiomycetes, and Phycomycetes; for example, Aspergillus niger and Penicillium notatum). However, it is mostly acquired from marine crustaceans such as shrimp shells. Chitosan-based composites often present superior chemical, physical, and mechanical properties compared to single chitosan by incorporating the benefits of both counterparts in the nanocomposites. The tunable surface chemistry, abundant surface-active sites, facilitation synthesize and functionalization, good recyclability, and economic viability make the chitosan-based materials potential adsorbents for effective and fast removal of a broad range of inorganic anions. This article reviews the different types of inorganic anions and their effects on the environment and human health. The development of the chitosan-based composites synthesis, the various parameters like initial concentration, pH, adsorbent dosage, temperature, the mechanism of adsorption, and regeneration of adsorbents are discussed in detail. Finally, the prospects and technical challenges are emphasized to improve the performance of chitosan-based composites in actual applications on a pilot or industrial scale.