Tuning Au/SiO₂ nanostructures from 1D to 3D interconnected nanotube networks using polycarbonate porous templates

We report a simple process, based on the combination of sol-gel deposition and nano-templating with polycarbonate membranes, for the synthesis of 1D to 3D free-standing silica (SiO₂) interconnected nanotube (NT) networks. The thickness and porosity of the SiO₂ nanotube walls can be, respectively, controlled by adjusting the ethanol amount in the sol-gel reaction mixture and by the addition or not of a porogen agent during the synthesis. Internal functionalization of 1D and 3D porous and non-porous SiO₂ NTs by Au nanoparticles (NPs) was then performed using electroless deposition leading to particle sizes ranging from 15 to 20 nm. Characterization of all these systems by SEM-EDX, TEM, ICP and XPS clearly demonstrated the impact of the porosity of SiO₂ on the amount and localization of Au NPs. Selective functionalization of the inner or the inner + outer surfaces of SiO₂ NTs was achieved by keeping or freeing the SiO₂ NTs from the template prior to electroless deposition, respectively. Moreover, UV-visible analysis confirmed plasmon resonance associated with Au NPs in all functionalized systems, paving the way to applications in many fields such as nano-medicine or (photo-)catalysis. In particular, the free-standing interconnected silica-based nanotube systems provide unique features of great interest for use in nanoscale fluidic bioseparation, sensing, and flow (photo)-catalytic chemistry, as demonstrated herein for the photodegradation of methylene blue.