Co-adsorption mechanisms of As(V) and Cd(II) by three-dimensional flower-like Mg/Al/Fe-CLDH synthesized by "memory
Donghui Chen1,2, Ruiyue Li1,2, Fangming Nan1,2
1School of Resource and Environmental Science, South-Central Minzu University, Wuhan, 430074, China.
Abstract:
Due to the different physical and chemical properties such as surface charge and ion morphology between As(V) and Cd(II), it is challenging to remove As(V) and Cd(II), especially at low concentrations. This study constructed a novel three-dimension nanocomposite adsorbent Mg/Al/Fe-CLDH (CFMA) by "hydrothermal + calcination method". And different initial concentration ratios (Cd: As=1: 2, 1: 1, 2: 1) were used to investigate the removal performance of CFMA for Cd(II) and As(V). When the concentration ratio Cd: As=1: 2, the residual concentrations of As(V) and Cd(II) were 8.7 μg/L and 4.2 μg/L, respectively, which met the drinking water standard; In the co-adsorption system, As(V) and Cd(II) influence each other's adsorption behavior due to the anionic bridge and shielding effect of As(V) on Cd(II), As(V) gradually changed from monolayer adsorption to multi-layer adsorption dominant, while Cd(II) gradually changed from multi-layer adsorption to monolayer adsorption dominant. In this paper, the structure-activity relationship between material structure and synchronous removal of arsenic and cadmium was clarified, and the mechanism of synchronous removal was revealed, which provided technical guidance for synchronous removal of As(V) and Cd(II) from non-ferrous metal smelting wastewater.
Related Concept Videos
Valence Bond Theory
Metallic Solids
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
Metal-Ligand Bonds
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
Complexation Equilibria: The Chelate Effect
Ladder Diagrams: Complexation Equilibria
The formation constant, K1, for the formation of Cd(NH3)2+ complex from cadmium and ammonia is 3.55 × 102. Log K1 (i.e. pNH3) is 2.55, and...


