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Step growth polymerization involves bi or multifunctional monomers. Bifunctional monomers react to form linear step growth polymers, whereas multifunctional monomers react to form non-linear or branched polymers.
As the step-growth polymerization involves step-wise condensation of monomers, the molecular weight also builds up eventually. Consequently, high molecular weight polymers are obtained at the late stages of the polymerization, where 99% of monomers have been consumed.
The extent of the...
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On the Creation and Optical Microstructure Characterisation of Additively Manufactured Foam Structures (AMF).

Anselm Heuer1, Maike Rees1, Kay A Weidenmann2

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Optical characterization of additively manufactured foam structures is crucial for process control. This study reveals that pore shape changes with orientation, not foaming behavior, and total porosity is fixed during slicing, necessitating analysis of pore networks for accurate foaming assessment.

Keywords:
Arburg plastic freeforming (APF)chemical blowing agentdegree of foamingentropy by Haralickfinenessfoam poresporosityprocess-related pores

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Area of Science:

  • Materials Science
  • Additive Manufacturing
  • Polymer Science

Background:

  • Plastic-based additive manufacturing is gaining traction for structural parts.
  • Additively manufactured foam structures offer lightweight design and extended functionality.
  • Optical characterization is vital for process adjustment and identifying structural changes in foams.

Purpose of the Study:

  • To develop sophisticated methods for optical characterization of additively manufactured foam structures.
  • To evaluate porosity, pore size, pore amount, and textural changes in foam structures.
  • To understand how orientation and process parameters affect foam structure characteristics.

Main Methods:

  • Microscope image analysis of manufactured and artificial additively manufactured foam structures.
  • Determination of porosity, pore size, pore amount, and textural change.
  • Evaluation of pore shape variations based on cutting plane orientation.

Main Results:

  • Additive structures exhibit changing pore shapes depending on cutting plane orientation, despite consistent foaming behavior.
  • Total porosity is determined during the slicing process and remains constant.
  • Degree of foaming cannot be inferred from total porosity but can be assessed via pore network formation.

Conclusions:

  • Caution is needed when interpreting changes in foam structures due to orientation-dependent pore shape variations.
  • The slicing process dictates total porosity in additive manufacturing.
  • Assessing the formation of large, process-related pore networks is key to determining the degree of foaming.