Surfactants in water and wastewater (greywater): Environmental toxicity and treatment options

Surfactant, an emerging pollutant present in greywater, raises the toxicity levels in the water body. Soap, detergent, and personal care items add surfactant to greywater. Due to excessive washing and cleaning procedures brought on by the COVID-19 pandemic, the release of surfactants in greywater has also increased. Considering the environmental toxicity and problems it creates during the treatment, it's essential to remove surfactants from the wastewater. This review intends to explain and address the environmental toxicity of the surfactant released via greywater and current techniques for surfactant removal from wastewater. Various physical, chemical, and biological methods are reported. Modern adsorbents such as hydrophilic silica nanoparticles, chitosan, fly ash, and iron oxide remove surfactants by adsorption. Membrane filtration effectively removes surfactants but is not cost-effective. Coagulants (chemical and natural coagulants) neutralize surfactant charges and help remove them as bigger particles. Electrocoagulation/electroflotation causes surfactants to coagulate and float. Microorganisms break down surfactants in microbial fuel cells to generate power. Surfactants are removed by natural processes and plants in constructed wetlands where traditional aerobic and anaerobic approaches use microbes to break down surfactants. Constructed wetlands, natural coagulation-flocculation, and microbial fuel cells are environmentally beneficial methods to remove surfactants from wastewater.