Chromium removal from chromium gypsum through microwave hydrothermal crystal phase regulation

Chromium gypsum (CG) is a common hazardous waste formed in chromium salt or electroplating industries. The trapped or lattice-doped CrO₄^2- in gypsum crystals are difficult to be reduced or removed by traditional methods, which will be re-oxidized or slowly released during long-term hypaethral storage. In this study, microwave hydrothermal treatment was applied to remove chromium in CG. Under optimal conditions (solid-liquid ratio of 1:5, 0.1 M sulfuric acid as liquid media, and 110 °C), over 99% of the chromium in CG can be removed within 10 min. XRD spectra indicated that 59.8% gypsum was transformed to from dihydrate gypsum to hemihydrate gypsum. The toxicity leaching test shows that chromium in CG is 377.0 mg/L before detoxification and 0.55 mg/L after detoxification, which proves that chromium in CG lattice can be efficiently removed. This work enables to significantly advance the dehydration phase transformation process of gypsum and release the heavy metal impurities within it more quickly and provides new possibilities to treat similar solid waste containing gypsum or minerals with hydration water.