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End-of-life tyre conversion to energy: A review on pyrolysis and activated carbon production processes and their
N H Zerin1, M G Rasul1, M I Jahirul1
1Fuel and Energy Research Group, School of Engineering and Technology, Central Queensland University, North Rockhampton, Queensland 4702, Australia.
Abstract:
The number of end-of-life waste tyres has increased enormously worldwide, which is one of the non-biodegradable Municipal Solid Waste (MSW) piling up in an open space for a long time. Every year, various types of tyres are released in the environment from different vehicles, such as trucks, buses, cars, motorcycles, and bicycles, which negatively impact the environment. Nowadays, waste tyres are treated in several ways, whereas thermochemical conversion is one of them, including combustion, gasification, incineration, and pyrolysis. Many literatures revealed that pyrolysis is a more environmentally friendly process than others since it can convert waste tyres into crude oil, char, and syngas without emitting harmful gases. In this study, the pyrolysis of tyres and the chemical activation of tyres are reviewed in terms of their kinetic behaviour. According to the literature, the most influential factors of the pyrolysis process are reactors, temperature, heating rate, residence time, feedstock size and catalyst. As the main ingredient of the tyre is rubber, tyre pyrolysis starts from 300 °C and completely decomposed nearly 550 °C. It can be found from literature that Pyrolysed tyre can produce 30-65% oil, 25-45% char and 5-20 % gas. It is also explained how the properties of active carbon (AC) are affected by activating conditions, including activation temperature, agent, the ratio of reagent mixture and others. Generally, pyrolytic char has surface area between 20 and 80 m2/g, whereas tyre-derived activated carbon's (TDAC) surface area varied from 90 to 970 m2/g. For large surface area and porous structure, TDAC has large application in purification and energy storage sector. The individuality of this article is to depict the entire pathway of AC production from waste tyres. The findings of this literature review help to improve technologies for producing activated carbon from waste tyres pyrolysed char.
