Metallic 1T-N-WS₂ /WO₃ Heterojunctions Featuring Interface-Engineered Cu-S Configuration for Selective...

Electrocatalytic carbon-dioxide reduction reactions (ECO₂ RR) are one of the most rational techniques to control one's carbon footprint. The desired product formation depends on deliberate reaction kinetics and a choice of electron-proton contribution. Herein the usage of novel CuS active centers decorated over stable 1T metallic N-WS₂ /WO₃ nanohybrids as an efficient selective formate conversion electrocatalyst with regard to ECO₂ RR is reported. The preferred reaction pathway is identified as *OCHO, which is reduced (by gaining H⁺  + e^- ) to HCOO^- (HCOO^- path) as the primary product. More significantly, at -1.3 V versus RHE yield of FE_HCOO ^- is 55.6% ± 0.5 with a J_geo of -125.05 mA cm^-2 for CuS@1T-N-WS₂ /WO₃ nanohybrids. In addition, predominant catalytic activity, selectivity, and stability properties are observed; further post-mortem analysis demonstrates the choice of material importance. The present work describes an impressive approach to develop highly active electrocatalysts for selective ECO₂ RR applications.