Surface activity, kinetics, thermodynamics and comparative study of adsorption of selected cationic and anionic dyes...

The discharge of dyes into the water body creates toxicity to aquatic organisms because of their aromatic structure and difficult degradation. So, the treatment of dye-contaminated wastewater is required before releasing it. In the present study, thermally treated (600 °C) and H₃PO₄ (55%)-functionalized bagasse, henceforth called thermochemically activated bagasse (TCAB), was synthesized as potential adsorbent for the effective removal of selected cationic and anionic dyes from their aqueous stream. TCAB characterization was done employing FT-IR, SEM, XRD, zeta potential, BET, and PZC techniques. The comparative study shows that the relative adsorption on TCAB followed the sequence, methyl red (185 mg/g) > safranin (178 mg/g) > congo red (146 mg/g) > brilliant green (139 mg/g) > malachite green (130 mg/g) > bromocresol green (94 mg/g). The adsorption efficiency was investigated concerning the effect of change in TCAB dose (0.05-0.3 g/100 mL), initial dye concentration (20-200 mg/L), pH (4.0-10.0), ionic strength (0.1-0.5 M KCl), urea concentration (0.1-0.5 M) and temperature (25-45 °C). The representative adsorption isotherms belong to typical L-type. The time-dependent dye removal was best explained by the pseudo-second-order (PSO) kinetic model (R² = 0.9859-0.9991), while equilibrium data were best explained by the Freundlich model (R² = 0.9881-0.9961). Thermodynamic study showed the spontaneous (ΔG⁰ <0) and exothermic nature (ΔH⁰ <0) of the adsorption of different cationic and anionic dyes. The cyclic adsorption ability of TCAB for different dyes was checked up to three cycles (185 to 168 mg/L for MR, 178 to 165 mg/L for SF, 146 to 130 mg/L for CR, 139 to 127 mg/L for BG, 130 to 114 mg/L for MG and 94 to 80 mg/L for BCG), and no significant decrease in the adsorption capacity was noticed. So, the present study provides valuable insights into the adsorption of cationic and anionic dyes onto H₃PO₄-functionalized bagasse. Addressing the adsorptive aspects enhances the clarity, reliability and applicability of the study's findings and contributes to its overall scientific impact.