Nanofiber-Reinforced Composite Gel Enabling High Ionic Conductivity and Ultralong Cycle Life for Zn Ion Batteries

Despite the impressive merits of gel electrolytes for aqueous Zn-ion batteries, it remains a significant challenge to design and develop the gel electrolyte with high ionic conductivity, excellent dimensional stability, and long cycle life. Herein, a composite electrolyte (PTP) with thermolastic polyurethane -poly(m-phenylene isophthalamide)  nanofiber-reinforced polyvinyl alcohol gel strategy is proposed for highly reversible Zn plating/stripping. Mechanically robust and ultrathin PTP contains functional groups for building ion migration channels and immobilizing water molecules, which accelerates Zn²⁺ migration and mitigates water-related side reactions. Thus, the Zn anodes exhibit excellent electrochemical performance involving high cycling stability (6500 h at 5 mA cm^-2 , 5 mA h cm^-2 ) and achieving an exceptional cumulative capacity of more than 16 000 mA h cm^-2 . This enhancement is well maintained when combined with MnO₂ cathode. This work provides a reasonable solution for stabilizing Zn anodes and also provides new ideas for the modification of nanofiber-reinforced gel electrolytes.