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Updated: Sep 30, 2026

Preparation and Use of Photocatalytically Active Segmented Ag|ZnO and Coaxial TiO2-Ag Nanowires Made by Templated Electrodeposition
Published on: May 2, 2014
In-situ formation of SrTiO3/Ti3C2 MXene Schottky heterojunction for efficient photocatalytic hydrogen evolution
Yujin Zhang1, Kailing Zhou2, Chunyu Yuan1
1School of Physics and Physical Engineering, Qufu Normal University, Qufu 273165, China.
Abstract:
Surface and interface engineering of composite photocatalysts are effective ways to enhance the dynamics of photo-generated charge carriers. In this work, SrTiO3/Ti3C2 MXene (STO/TC) Schottky heterojunction is constructed by in-situ growth of SrTiO3 (STO) on Ti3C2 MXene (TC) through Sr(OH)2 etching the surfaces of TC. This in-situ growth strategy not only creates the tight chemically bonded interfaces by SrTiO3 nanoparticles uniformly anchoring on the surface of two-dimensional Ti3C2 MXene nanosheets for promoting the photo-generated charge carrier separation, but also introduces surface Ti vacancies as the efficient catalytic active sites to accelerate the charge carrier transfer process for efficient hydrogen production. The photocatalytic system constructed by interface and surface engineering optimizes the photo-generated charge carrier dynamics and refines the photocatalytic hydrogen evolution performance (6.8 times higher than pristine SrTiO3) and stability. This work is expected to provide an alternative strategy to construct highly efficient photocatalysts with hydrogen evolution.
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