Cadmium and zinc isotope compositions indicate metal sources and retention mechanisms in different soil particle size fractions

Soil particle size may significantly affect metal distribution and stable isotopic behavior. Here, two soils were separated into four particle size fractions, namely fine sand, silt, fine silt, and colloidal particles and used to determine cadmium (Cd) and zinc (Zn) concentrations and isotope compositions. Concentrations of Cd and Zn were generally enriched in the finer particles and positively correlated with the iron (Fe) and manganese (Mn) oxide contents. However, Cd concentration in the fine sand was higher than in the silt fraction due to the higher soil organic matter contents in the former particle fraction. The maximum δ^114/110Cd value was found in the colloidal particles (-0.02 and 0.01‰) of both soils while the minimum was in the silt particles (-0.12 and 0.06‰). Incorporation into the mineral lattice of Fe and Mn oxides is suggested to explain the slight enrichment of heavy Cd isotopes in the colloidal fraction. The similar δ⁶⁶Zn values of the four particle fractions (0.20-0.29‰ with a mean of 0.25‰) indicate similar Zn sources in different particle sizes. Metal isotopic fingerprint of different soil particle size fractions provides further insight into the underlying metal retention mechanisms within soil micro-zones and helps in tracing metal sources and biogeochemical processes.