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Towards Biomimicking Wood: Fabricated Free-standing Films of Nanocellulose, Lignin, and a Synthetic Polycation
Published on: June 17, 2014
Regenerated cellulose/polyvinyl alcohol composite films with high transparency and ultrahigh haze for multifunctional
Caimei Zhao1, Xinhu Gong1, Xiaotian Lin1
1Key Laboratory for Biobased Materials and Energy of Ministry of Education, College of Materials and Energy, South China Agricultural University, 483 Wushan Road, Guangzhou 510642, China; Guangdong Laboratory for Lingnan Modern Agriculture, 483 Wushan Road, Guangzhou 510642, China.
Abstract:
In this study, cellulose composite films (CCFs) were fabricated through controllable dissolution and regeneration process of cellulose with the addition of polyvinyl alcohol (PVA). The competition of hydrogen bond site between cellulose and PVA led to partial dissolution of cellulose and maintained morphology of micron fibers with width range from 14.55 to 16.16 μm, which served as in-situ visible light scatterers. With this unique micron structure, the obtained CCF exhibited high transparency up to 90.5 % at 550 nm and ultrahigh haze up to 96 %. Interestingly, CCF could be used as hazy and flexible substrate, such as scattering lamp covers for indoor light management, anti-glare screen protectors and anti-reflection layers of solar cell devices. Among them, the efficiency of the solar cell device could be improved by 10.38 % with the help of a low-cost, excellent-performance CCF.
