Integrating multifunctional highly efficient flame-retardant coatings with superhydrophobicity, antibacterial...

There has been a growing interest in bio-based flame-retardant coating layer with good antibacterial activity for cotton fabric owing to the arising environmental pollution and viral and bacterial infectious risks. In this study, multifunctional flame-retardant coatings with superhydrophobicity and antibacterial property were integrated on cotton fabric through two-step method. The first layer of phosphorylated chitosan (PCS) biobased coating (C4) endowed the fabric highly efficient flame retardancy and antibacterial activity, and the second layer of modified poly(2-hydroxyethyl methacrylate phosphate ester) (PHEMAP) coating by perfluorooctyltriethoxysilane (P/F) provided the fabric excellent superhydrophobicity and self-cleaning ability. The C4-P/F fabric exhibited a shorter damage length of only 6.2 cm and achieved a higher char yield of 22.3 % than the C4 fabric in the vertical combustion test, and the limited oxygen index of the C4-P/F fabric increased to 32.5 %. The water contact angle (WCA) of the C4-P/F fabric reached above 150 ^o. Moreover, the C4-P/F fabric exhibited excellent antibacterial activity against Escherichia coli and Staphylococcus aureus. The highly efficient flame-retardant, superhydrophobic, antibacterial fabric is promising in home and public decoration, fire protection fields.