Electrocatalytic Water Oxidation Activity-Stability Maps for Perovskite Oxides Containing 3d, 4d and 5d Transition...

Improving catalytic activity without loss of catalytic stability is one of the core goals in search of low-iridium-content oxygen evolution electrocatalysts under acidic conditions. Here, we synthesize a family of 66 SrBO₃ perovskite oxides (B=Ti, Ru, Ir) with different Ti : Ru : Ir atomic ratios and construct catalytic activity-stability maps over composition variation. The maps classify the multicomponent perovskites into chemical groups with distinct catalytic activity and stability for acidic oxygen evolution reaction, and highlights a chemical region where high catalytic activity and stability are achieved simultaneously at a relatively low iridium level. By quantifying the extent of hybridization of mixed transition metal 3d-4d-5d and oxygen 2p orbitals for multicomponent perovskites, we demonstrate this complex interplay between 3d-4d-5d metals and oxygen atoms in governing the trends in both activity and stability as well as in determining the catalytic mechanism involving lattice oxygen or not.