Facet-dependent U(VI) removal of hematite with confined ferrous ions

The presence of ferrous minerals has been demonstrated to have a significant impact on the destiny, migration, and availability of uranyl (U(VI)) in natural surroundings. The iron oxide/Fe(II) system is a multifaceted iron reduction system anchored to surfaces, encompassing various forms of iron and ferrous ions. Several studies have investigated the effectiveness of adsorbed ferrous iron on iron-based minerals to facilitate the reduction of heavy metal ions and radioactive nuclides. A range of techniques for characterization, including X-ray photoelectron spectroscopy (XPS) and Mössbauer spectroscopy, were employed to explore the process of U(VI) adsorption and deposition, focusing on the limited region containing ferrous iron on the exposed crystalline surface of hematite. In this specific investigation, two kinds of hematite nanocrystals primarily exposing {001} and {012} crystal facets, referred to as HNPs and HNCs, were synthesized. Their ability to remove U(VI) was examined. Ferrous ions (Fe(II)) adsorbed onto the surface of hematite nanocrystals significantly enhanced the efficiency of U(VI) remediation. Furthermore, the HNCs/Fe(II) system showed better U(VI) reduction ability than the HNPs/Fe(II) system. Remarkably, HNCs produced and consumed more electrons and hydroxyl radicals, indicating a more intense response. This finding serves to highlight the significance of their role in interfacial effects and in predicting the spatial distribution of U(VI) in aqueous systems.