Phase-Tailoring W_x V_1-x O₂ Meta-Nanofiber Enables Temperature-Editing Energy Control

Room-temperature phase change materials (RTPCMs) exhibit promise to address challenges in thermal energy storage and release, greatly aiding in numerous domains of human existence and productivity. The conventional RTPCMs undergo inevitable volume expansion, structural collapse, and diffusion of active ingredients while maintaining desirable phase change enthalpy and ideal phase change temperature. Here, a sol-gel 1D-induced growth approach is presented to fabricate meta nanofibers (Meta-NFs) comprised of vanadium dioxide with monoclinic crystal structure, and further achieve the editable phase change temperature from 68 to 37 °C through W-doping, which allowed for tailored length variation of the zigzag V-V bond. Subsequently, Meta-NFs are assembled into 3D aerogels with self-standing architecture, thereby enabling the independent use of the RTPCMs. The obtained metamaterials demonstrate not only the temperature-editing solid-solid phase transition, but also the stiffness of the ceramic matrix, exhibiting the thermal energy control capability at room temperature (37 °C), thermal insulation properties, temperature resistance, and flame retardancy. The effective creation of these fascinating metamaterials might offer new insights for next-generation and self-standing solid-solid RTPCMs.