Polarization Processes in Nafion Composite Membranes Doped with Rare-Earth Metals

Dielectric spectroscopy (frequency range f = 10⁰…10⁷ Hz and temperatures T = 293…403 K (accuracy 0.5 K), measuring voltage applied to the sample was 1.0 V) was used to study composite materials based on perfluorosulfonic membranes with inclusions of rare-earth elements, in particular, europium (III) and terbium (III) chlorides. The dispersion of the permittivity and the presence of maxima, corresponding to losses, were revealed, which indicates that relaxation processes of various natures were present. The membrane layers under investigation are characterized by relaxation parameters that correspond to a symmetrical distribution of relaxers over relaxation times. The spectrum of relaxers changed when terbium and europium metal impurities were introduced into the polymer matrix. The investigation of these polymer systems demonstrated a power-law dependence of the specific conductivity on frequency. A decrease in the exponent with increasing temperature indicates the existence of a traditional hopping mechanism for charge transfer. The observed changes in the dielectric permittivity and specific conductivity are due to a change in the nature of polarization processes because of the strong interaction of metal (terbium and europium) ions with the polymer matrix of Nafion.