Rainwater extracting characteristics and its potential impact on DBPs generation: A case study

Frequent extreme precipitation events due to global warming can lead to large amounts of pollutants entering source water bodies via surface runoff and wet deposition, thus posing a threat to water supply security. In order to better understand the source characteristics and leaching mechanisms of rainwater dissolved organic matter (DOM), as well as its disinfection by-products formation potential (DBPsFP) during disinfection processes, rainwater samples were collected and extracting experiments were conducted. Three components were identified in rainwater through Parallel factor (PARAFAC) analysis, which were microbial humic-like component C1 (63.1 %), protein (tryptophan-like) component C2 (28.9 %), marine or terrestrial humic-like component C3 (8.1 %). The average molecular weight of rainwater fractions was ordered: hydrophobic neutral (HON) < hydrophobic bases (HOB) < hydrophobic acidic (HOA) < hydrophilic (HIS). The HOA and HON fractions of rainwater were the dominant precursors of trihalomethanes (THMs), while the rainwater HON fraction and hydrophilic fraction were the main precursor of haloacetic acids (HAAs) and trihloroacetonitrile (TCAN), respectively. Subsoil extracts had a higher concentration of dissolved organic carbon (DOC) and total dissolved nitrogen (TDN) than topsoil extracts. Partial least squares path modeling (PLS-PM) demonstrated that the extraction temperature was the dominant factor affecting the abundance of DOM in the topsoil extracts (R² = 0.28), while the extraction time accounted more for the abundance of fluorescence substance and physicochemical indices in the subsoil extracts (R² = 0.23 and 0.32, respectively). These results provide key information for controlling the impacts of global warming, in particular the risk of water sources being heavily contaminated by request rainfalls.