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Updated: Jul 15, 2025

Novel Techniques for Observing Structural Dynamics of Photoresponsive Liquid Crystals
Published on: May 29, 2018
Dimension-Dependent Phase Transitions, Ferroelasticity, and Photoluminescence in Hybrid Organic-Inorganic Materials
Peng Cao1, Yu-Ting Liu1, Jin-Tao Men1
1Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics and School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, People's Republic of China.
Abstract:
[(CH3)3P(CH2)2OH]2Cd3(SCN)8 (1) and [(CH3)3P(CH2)2OH]Cd(SCN)3 (2) were obtained with completely different structures and properties under the same synthesis conditions. Compound 1, showing green fluorescence, has a rare three-dimensional 4,6-connected fsh topology having (43.63)2(46.66.83) Schläfli notation, while compound 2 with blue-violet phosphorescence displays a one-dimensional perovskite structure with an infinite {[Cd(SCN)3]-}∞ chain and exhibits both ferroelastic and dielectric switching characteristics.
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