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Improving the cycling stability of LiNi0.8Co0.1Mn0.1O2 by boron doping to inhibit Li/Ni mixing
Ziru Hu1, Donghong Duan1, Haorui Wang1
1College of Chemical Engineering and Technology, Taiyuan University of Technology, Taiyuan, 030024, Shanxi, China.
Abstract:
Boron doping significantly reduces the Li/Ni cation mixing of LiNi0.8Co0.1Mn0.1O2, decreases the charge transfer resistance, and improves the reversibility of the H2-H3 phase transition at 4.2 V. Among similar materials, the cathode material with 1.0 mol% boron doping shows excellent cycling performance, with capacity retention of 96% after 200 cycles at 50 °C.
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