Improved solid/liquid separation performance of hydrochar from sludge via hydrothermal carbonization

A solid-liquid separation process is crucial for the utilization of hydrochar from biomasses through hydrothermal carbonization (HTC). This study aimed to evaluate the separation performance of hydrochar from coking sludge (CS) and municipal sludge (MS) via HTC and propose its mechanistic insights. The results indicated that the separation performance of hydrochar was enhanced, and relatively severe hydrothermal temperatures exerted a relatively stronger dewatering effect (53.25% and 77.05% reductions in the total water contents in CS and MS, respectively) and a superior separation efficiency (the specific resistance to filtration of products obtained from CS and MS decreased form 7.21 × 10¹¹ and 2.46 × 10¹² to 1.92 × 10¹⁰ m/kg and 2.14 × 10¹¹ m/kg, respectively). Mechanism investigation involved analyzing the surface functional groups of hydrochar and changes in organic components. It was demonstrated that the improvement in dewatering effect predominantly resulted from the release of bound water due to the decomposition of carbohydrates and proteins. Specifically, the release of bound water depended on the decomposition of carbohydrates at 180 °C, while it relied on the decomposition of proteins in the 210-300 °C range. Compared with particle size, the hydrophilicity of the particle played a more important role in improving the separation efficiency. The HTC reaction eliminated hydrophilic groups, such as hydroxyl and carboxyl groups, and induced the formation of aromatic structures, thus reducing the hydrophilicity of hydrochar particles. Moreover, it was found that the lower heating value of hydrochar from CS and MS increased from 3.51 to 1.94 to 8.32 and 4.60 MJ/kg due to the improvement of the separation efficiency. These comprehensive findings provide valuable mechanistic insights into the solid-liquid separation process and controlling the dewaterability of hydrochar.