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A lithium-scandium sulfate with second-harmonic generation response and deep-ultraviolet transparency
Zi-Long Geng1,2, Hong-Xin Tang1, Rui-Biao Fu1
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. furb@fjirsm.ac.cn.
Abstract:
A new beryllium-free deep-UV transparent NLO crystal Li(H2O)2Sc(SO4)2 features a two-dimensional [Sc(SO4)2] framework consisting of twisted [Sc3S4O9] units decorated by [LiO2(H2O)2] groups into a unique layer. Remarkably, Li(H2O)2Sc(SO4)2 exhibits a phase-matching SHG response of 0.7 × KDP and a deep-UV cutoff edge below 190 nm.
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