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Design, Synthesis, and Photochemical Properties of Clickable Caged Compounds
Published on: October 15, 2019
Photo-controllable binding and release of HP2O73- using an azobenzene based smart macrocycle
Shenglun Xiong1, Yi Zhang1, Yunqi Jiang1
1State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, No. 2 Lushan Road (S), Yuelu District, Changsha 410082, P. R. China. heqing85@hnu.edu.cn.
Abstract:
Herein, we describe the design and synthesis of an unusual azobenzene-bearing macrocycle 1, whose trans isomer was found able to 100% transform into its cis configuration under photoirradiation, for selectively recognizing HP2O73- with reversibly photo-controllable binding and release properties.
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