A novel salt-barrier method of preparation flexible temperature resistant full-component nanocellulose membranes

With the simplification and diversification of separation technologies, nanocellulose membranes have become widely used as insulating materials. Recently, study of nanocellulose membrane modification has become a hot topic. However, the application of nanocellulose membrane has been limited due to their inadequate heat resistance and flexibility. Herein, based on the pyrolytic and thermoplastic properties of cellulose, we innovatively introduced a salt barrier scheme to regulate the degree of hydrogen bonding and thermoplastic bonding between fibers. This was achieved by adding a salt barrier agent, NaCl, in the middle of the nanocellulose to prepare and obtain flexible, high-temperature-resistant nanocellulose film materials. The full-component cellulose films thus prepared exhibited high tensile strength (8 MPa), excellent flexibility (105 mN), high electrical breakdown strength (67 KV/mm), and volume resistivity meeting the standard of insulation materials (3.23 × 10¹³ Ω·m). This scheme adheres to the principles of low cost, green, non-toxic and non-hazardous, providing a brand new approach for the research and development of high temperature resistant cellulose membrane materials, which is of significant commercial value and industrialization prospect.