Dielectric and Mechanical Properties of PDMS-La₂Ba₂XZn₂Ti₃O₁₄ (X = Mg/Ca/Sr) Nanocomposites

Flexible polydimethylsiloxane-La₂Ba₂XZn₂Ti₃O₁₄ (X = Mg/Ca/Sr) [PDMS-LBT] nanocomposites with high permittivity (dielectric constant, k) are prepared through a room-temperature mixing process. The LBT nanoparticles used in this study are prepared through a high-temperature solid-state reaction. It is observed that LBT (X = Mg/Ca) nanoparticles are spherical in nature, with particle size ∼20 nm, as observed from the HRTEM images, whereas LBT (X = Sr) nanoparticles are cubical in nature with particle size ≥100 nm. These LBT (X = Mg/Ca/Sr) nanoparticles are crystalline in nature, as apparent from the XRD analysis and SAED patterns. The permittivity of LBT nanoparticles is higher when "Ca" is present in place of "X". These three oxides show a temperature-dependent dielectric behavior, where LBT nanoparticles with "Sr" show a sharp change in permittivity at a temperature of ∼105 °C. These kinds of oxide materials, especially LBT (X = Sr) nanoparticles/oxides, can be used in dielectric/resistive switching devices. The effect of LBT nanoparticle concentration on the dielectric and mechanical properties of PDMS-LBT nanocomposites is widely studied and found that there is a significant increase in dielectric constant with an increase in the concentration of LBT nanoparticles. There is a decrease in the volume resistivity with the increase in the LBT nanoparticle concentration. All the PDMS-LBT nanocomposites have low dielectric loss (ε″) compared to the dielectric constant value. It is found that both permittivity (ε') and AC conductivity (σ_ac) of PDMS-LBT composites are increased with the temperature at a frequency of 1 Hz. The % elongation at break (% EB) and tensile strength (TS) decrease with the LBT nanoparticle concentration in the matrix PDMS, which is due to the non-reinforcing behavior of LBT nanoparticles. The distribution and dispersion of LBT nanoparticles in the matrix PDMS are observed through HRTEM and AFM/SPM.