Water-Based Additive-Free Chromic Inks for Printing of Flexible Photochromics and Electrochromics

Digital inkjet printing has become one of the most convenient and efficient technologies for coating chromic materials on flexible substrates with complicated patterns. However, the development of water-based, additive-free chromic inks for inkjet printing still remains a challenge. Herein, three ammonium-functionalized colorless viologen derivatives AV, APV, and AQV with excellent water solubilities are utilized as chromes in the chromic inks due to their excellent photochromic and electrochromic properties. Water, ethanol, and ethylene glycol are selected as cosolvents, and their contents in this ternary solvent system have been optimized to achieve comprehensive rheological properties. With the H₂O:EtOH:EG weight ratio of 8:1:7, the chromic ink based on AV realizes a viscosity of 4.69 mPa·s, a surface tension of 45.13 mN/m, and a Z value of 3.87. Without adding any additive, the as-prepared chromic inks can be printed on flexible substrates, such as paper and poly(ethylene terephthalate) (PET) films, by a conventional inkjet printer with inherent high resolutions. The printed patterns are initially invisible due to the colorless characteristics of the chromic inks. Interestingly, the printed films are responsive to both light and electric stimuli. Upon irradiation by UV light, a series of sentences with font sizes from 5 to 12 points and four quick response codes with different lattice resolutions clearly appear on the printed paper. Meanwhile, after printing on an indium tin oxide-coated PET substrate, electrochromic devices (ECDs) can be facilely fabricated by covering a hydrogel electrolyte on the printed films. Upon application of different potentials, the assembled ECDs exhibit "Peking Opera facial makeup" patterns with different colors. Therefore, the developed water-based additive-free chromic inks can be utilized for information display and encryption applications.