Polycyclic aromatic hydrocarbons (PAHs) in coal preparation plant products: A contributor to environmental pollution

Coal and coal gangue are petrogenic sources of polycyclic aromatic hydrocarbons (PAHs), which cause adverse impacts on the environment. Raw coal, cleaned coal, slime, slack gangue, and lump gangue from the Pingshuo No. 1 Coal Preparation Plant, China, were analyzed to determine the concentrations and compositions of 16 priority parent PAHs (16PAHs) and their alkylated derivatives (aPAHs). The ∑₁₆PAH and ∑aPAH concentrations in the samples ranged from 18.7 to 139.2 mg/kg and 22.2 to 262.3 mg/kg, respectively, and ranked as follows: cleaned coal > raw coal > slime > lump gangue > slack gangue. Coal gangues had a higher proportion and lower degree of alkylation of 4-6-ring PAHs than coals. A summary analysis of references related to coal and coal gangue diagnostic ratios showed that their ratios could not be used to differentiate them from other PAH sources, indicating that the release of particulate coal and coal gangue would increase the uncertainty of environmental PAH identification results. The diagnostic ratios of coal gangue were relatively concentrated, and comparing the ratio distribution could reveal the coal gangue source PAHs. The toxicity risk of slack gangue was higher than that of lump gangue based on the benzo[a]pyrene-equivalent concentration; hence, more attention should be given to its escape to the environment.