High-mass-loading cobalt iron phosphide@nickel vanadium layered double hydroxide heterogeneous nanosheet arrays for...

Designing multidimensional heterostructures on flexible substrates is an efficient approach to resolve the low energy density of supercapacitors. Herein, a three-dimensional (3D) porous cobalt iron phosphide (CoFeP)@nickel vanadium-layered double hydroxide (NiV-LDH) heterostructure has been prepared anchored on carbon cloth (CC) substrate. In this nanoarchitecture, NiV-LDH nanosheets are densely wrapped on the surface of CoFeP nanosheets, which forms a hierarchically porous framework with an enlarged surface area and accessible pore channels. Benefiting from the strong interaction and synergistic effect between CoFeP and NiV-LDH, the well-defined heterostructure can realize simultaneously rich redox active sites, rapid reaction dynamics, and good structural stability. Thus, the binder-free CoFeP@NiV-LDH electrode with a high mass loading of 6.47 mg cm^-2 displays a significantly increased specific capacity of 903.1C g^-1 (2.35C cm^-2) at 1 A g^-1 and enhanced rate capability when compared to pristine CoFeP and NiV-LDH. Additionally, the assembled hybrid supercapacitor (HSC) yields an energy density of 77.9 Wh kg^-1/0.98 Wh cm^-2 and excellent long-term stability. This research proposes a rational route for designing heterogeneous micro-/nanoarchitectures with commercial-level mass loading for the practical application of high-energy-density supercapacitors.