Rapid marine degradable poly(butylene oxalate) by introducing promotion building blocks

The design and development of high-performance marine-degradable plastics have long been considered a superior strategy to address marine plastic pollution. To achieve a balance between rapid marine degradability and high performance of polyester plastics, this work designed two series of poly(butylene oxalate) (PBOx) copolymers with intrinsic hydrolysis ability using poly(ethylene oxalate) (PEOx) and poly(glycolic acid) (PGA) as promotion building blocks. The synthesis process, crystallization properties, barrier performance, and mechanical properties of copolymers were comparatively investigated. Additionally, the marine degradability of copolymers received specific focus. The theoretical calculation demonstrated that the introduction of promotion blocks reduced the hydrolysis energy barrier of the copolymers. In general, the results revealed the advantages of PBEOx copolymer in satisfying practicality and better regulating marine degradability. The high gas barrier performance, suitable thermal properties, tunable mechanical properties, and rapid marine degradability endow the copolymer as a promising candidate toward sustainable and marine-degradable plastics.