Thermally Activated Delayed Fluorescence Emitters Based on a Special Tetrahedral Silane Core

Based on the tetraphenylsilane skeleton, a new class of thermally activated delayed fluorescence (TADF) molecules have been designed and synthesized. Benefiting from the unique tetrahedron architecture of tetraphenylsilane, the intermolecular distance between TADF units can be enlarged and thus weakened the aggregation-induced quenching of triplet excitons. By adjusting the numbers of TADF subunits, the spin-orbit coupling processes can be controlled, leading to efficient up-conversion processes. The related OLEDs are fabricated through the solution processing technology, and pure-blue and green electroluminescence were observed with maximum external quantum efficiencies (EQE_max) of 6.6 and 13.8% as well as Commission Internationale de l'Eclairage coordinates of (0.14, 0.15) and (0.25, 0.45), respectively. This study provides a new idea for designing color-tunable TADF emitters through spatial structure regulation.