Search research articles

ABOUT JoVE

Overview Leadership Blog JoVE Help Center

AUTHORS

Publishing Process Editorial Board Scope & Policies Peer Review FAQ Submit

LIBRARIANS

Testimonials Subscriptions Access Resources Library Advisory Board FAQ

RESEARCH

JoVE Journal Methods Collections JoVE Encyclopedia of Experiments Archive

EDUCATION

JoVE Core JoVE Business JoVE Science Education JoVE Lab Manual Faculty Resource Center Faculty Site

Terms & Conditions of Use

Related Concept Videos

Interfacial Electrochemical Methods: Overview

Interfacial Electrochemical Methods: Overview

Interfacial electrochemical methods focus on the phenomena occurring at the boundary between an electrode and a solution, as opposed to bulk methods that concentrate on the solution's overall properties. These interfacial methods are classified as either static or dynamic based on the presence of a nonzero current in the electrochemical cell and the consistency of analyte concentrations. Static methods, such as potentiometry, measure the cell's potential without any significant current...

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by

Same author

Multifunctional electrochemical memory stabilized by phase coexistence.

Science advances·2026

Same author

Ion-Electron Coupling-Driven Redox Behavior in Metal-Organic Frameworks.

Journal of the American Chemical Society·2026

Same author

High-temperature chemical oxidation pathways in lithium-ion batteries: mechanistic insights into ethylene carbonate decomposition.

Chemical science·2026

Same author

Nanoengineering of non-aqueous liquid electrolyte solutions for future lithium metal batteries.

Nature nanotechnology·2026

Same author

Revealing key structures for reversible sulfur redox in amorphous polymeric sulfur.

Nature materials·2026

Same author

Evolution and Degradation Patterns of Electrochemical Cells Based on the Analysis of Interfacial Phenomena at Li Metal Anode/Electrolyte Interfaces.

The journal of physical chemistry. C, Nanomaterials and interfaces·2025

Search research articles

Related Experiment Video

Updated: Jul 12, 2025

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

Knowledge-driven design of solid-electrolyte interphases on lithium metal via multiscale modelling.

Janika Wagner-Henke¹, Dacheng Kuai^2,3, Michail Gerasimov¹

¹Institute for Applied Materials - Electrochemical Technologies, Karlsruhe Institute of Technology, Karlsruhe, 76131, Germany.

Nature Communications

|October 26, 2023

Summary

Researchers modeled solid electrolyte interphase (SEI) formation on lithium metal. They found electrolyte composition significantly impacts SEI structure and properties, enabling strategies for improved battery performance and safety.

More Related Videos

Screening of Coatings for an All-Solid-State Battery Using In Situ Transmission Electron Microscopy

Screening of Coatings for an All-Solid-State Battery Using In Situ Transmission Electron Microscopy

Published on: January 20, 2023

Identification and Quantification of Decomposition Mechanisms in Lithium-Ion Batteries; Input to Heat Flow Simulation for Modeling Thermal Runaway

Identification and Quantification of Decomposition Mechanisms in Lithium-Ion Batteries; Input to Heat Flow Simulation for Modeling Thermal Runaway

Published on: March 7, 2022

Related Experiment Videos

Last Updated: Jul 12, 2025

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

Screening of Coatings for an All-Solid-State Battery Using In Situ Transmission Electron Microscopy

Screening of Coatings for an All-Solid-State Battery Using In Situ Transmission Electron Microscopy

Published on: January 20, 2023

Identification and Quantification of Decomposition Mechanisms in Lithium-Ion Batteries; Input to Heat Flow Simulation for Modeling Thermal Runaway

Identification and Quantification of Decomposition Mechanisms in Lithium-Ion Batteries; Input to Heat Flow Simulation for Modeling Thermal Runaway

Published on: March 7, 2022

Area of Science:

Materials Science
Electrochemistry
Computational Modeling

Background:

Lithium metal's high energy density makes it ideal for advanced energy storage.
Solid electrolyte interphase (SEI) formation is critical for lithium metal battery performance and safety.
Current understanding of SEI formation mechanisms, especially electrolyte influence, is limited.

Purpose of the Study:

To develop an in-depth model for initial SEI formation on lithium metal.
To analyze SEI formation at larger length and time scales than previous studies.
To understand how electrolyte composition impacts SEI structure and properties.

Main Methods:

A multiscale kinetic Monte Carlo/continuum modeling approach was employed.
Simulations focused on initial SEI formation in a carbonate-based electrolyte.
Analysis covered electrolyte and salt decomposition processes.

Main Results:

A layered, inorganic SEI (LiF on Li₂CO₃/Li) formed within 1 µs.
Low Li⁺ concentrations led to a mosaic-like, partly organic SEI.
Increased salt concentration accelerated lithium metal surface passivation.

Conclusions:

Electrolyte composition critically governs SEI formation and characteristics.
Model provides insights into SEI development for enhanced lithium metal batteries.
Findings support knowledge-driven engineering of SEI layers for improved battery design.