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Updated: Jul 12, 2025
Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
Mössbauer and X-ray Diffraction Spectroscopy of High-Iron Bauxites from Kazakhstan
Adilkhan Shokanov1, Mikhail Vereshchak2, Irina Manakova2
1Abai Kazakh National Pedagogical University, Dostyk Av. 13, Almaty 050010, Kazakhstan.
Abstract:
The bauxite ores of Kazakhstan were analyzed using Mössbauer spectroscopy, X-ray diffraction and an X-ray fluorescence analysis. Experimental data on the structural-phase composition of bauxites were obtained, and the features of the iron-bearing minerals within them were revealed. The studied bauxites were high in iron. The magnetic part of bauxite was mainly represented by aluminohematite with a concentration of CAl = 3.34-5.73 at.%, alongside goethite in small amounts. The predominant phase in the bauxite samples was the alumina-bearing mineral gibbsite with a well-crystallized monoclinic lattice. The main siliceous mineral of bauxite is kaolinite, which showed distorted octahedral positions in a number of samples. Siderite amounts were found to vary in the range of 0-15 at.% in the present iron-bearing minerals. Ilmenite was also present in the bauxite of some deposits; anatase was found in all bauxites and was the final product of ilmenite decomposition in the weathering crust.
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