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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
Synthesis and Photocatalytic Activity of Novel Polycyclopentadithiophene
Farah Zayanah Ahmad Zulkifli1, Moeka Ito1, Takahiro Uno1
1Division of Applied Chemistry, Graduate School of Engineering, Mie University, 1577 Kurimamachiya-cho, Tsu 514-8507, Mie, Japan.
Abstract:
A novel π-conjugated polymer based on cyclopentadithiophene (CPDT) and poly(4,4']-(((4Hcyclopenta[2,1-b:3,4-b']dithiophene-4,4-diyl)bis(ethane-2,1-diyl))bis(oxy))bis(4-oxobutanoic acid)) (PCPDT-CO2H) was prepared as a sparingly soluble material. The generation of hydroxyl radicals from PCPDT-CO2H in water was confirmed by using coumarin as a hydroxyl radical indicator. Furthermore, PCPDT-CO2H was found to catalyze the oxidative hydroxylation of arylboronic acid and the oxidation of benzaldehyde, indicating that PCPDT-CO2H can be a promising candidate for metal-free and 100% organic heterogeneous photocatalysts.
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