Effect of Lithium Salts on the Properties of Cassava Starch Solid Biopolymer Electrolytes

This study evaluates the effect of lithium salts on the structural, electrochemical, and thermal properties of cassava starch solid biopolymer electrolytes (SBPEs). Films of SBPEs were synthesized using plasticizing agents and lithium salts (LiCl, Li₂SO₄, and CF₃LiSO₃) via thermochemical method. The SBPEs with lithium salts exhibited characteristic FTIR bands starch, with slight variations in the vibration oxygen-related functional groups compared to salt-free biopolymer spectra. The R_COH/COC index (short-range crystallinity) was higher in the films synthesized without lithium salt and the lowest value was established in the films synthesized with Li₂SO₄. Thermal degradation involved dehydration between 40 to 110 °C and molecular decomposition between 245 to 335 °C. Degradation temperatures were close when synthesized with salts but differed in films without lithium salt. DSC revealed two endothermic processes: one around 65 °C linked to crystalline structure changes and the second at approximately 271 °C associated with glucose ring decomposition. The electrochemical behavior of the SBPEs varied with the salts used, resulting in differences in the potential and current of peaks from the redox processes and its conductivity, presenting the lowest value (8.42 × 10^-5 S cm^-1) in the SBPE films without salt and highest value (9.54 × 10^-3 S cm^-1) in the films with Li₂SO₄. It was concluded that the type of lithium salt used in SBPEs synthesis affected their properties. SBPEs with lithium triflate showed higher molecular ordering, thermal stability, and lower redox potentials in electrochemical processes.