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Trends in Lattice Energy: Ion Size and Charge02:54

Trends in Lattice Energy: Ion Size and Charge

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An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
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Boundary Conditions for Current Density01:25

Boundary Conditions for Current Density

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Current density becomes discontinuous across an interface of materials with different electrical conductivities. The normal component of the current density is continuous across the boundary.
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Metal-Semiconductor Junctions01:24

Metal-Semiconductor Junctions

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The contact of metal and semiconductor can lead to the formation of a junction with either Schottky or Ohmic behavior.
Schottky Barriers
Schottky barriers arise when a metal with a work function (Φm) contacts a semiconductor with a different work function (Φs). Initially, electrons transfer until the Fermi levels of the metal and semiconductor align at equilibrium. For instance, if Φm > Φs, the semiconductor Fermi level is higher than the metal's before contact. The...
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Carrier Transport01:21

Carrier Transport

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The generation of electrical current in semiconductors is fundamentally driven by two mechanisms: drift and diffusion. These processes are essential for the functionality and performance of semiconductor-based devices.
Drift Current:
The drift of charge carriers is started by an external electric field (E). Charged particles, such as electrons and holes, experience an acceleration between collisions with lattice atoms. For electrons, this results in a drift velocity (vd) given by:
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Current Density01:21

Current Density

4.1K
The total amount of current flowing through one unit value of a cross-sectional area is referred to as current density. If the current flow is uniform, the amount of current flowing through a conductor is the same at all points along the conductor, even if the conductor area varies. The current density consists of the local magnitude and direction of the charge flow, which varies from point to point. Current density is measured in amperes per meter square, and direction is defined as the net...
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Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

26.6K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
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Related Experiment Video

Updated: Jul 12, 2025

Analysis of Contact Interfaces for Single GaN Nanowire Devices
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Correlating the Microstructure and Current Density of the Li/Garnet Interface.

Cheng Ouyang1, Hongpeng Zheng1, Qiwen Chen1

  • 1State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China.

ACS Applied Materials & Interfaces
|October 28, 2023
PubMed
Summary

Optimizing solid-state battery electrolytes by controlling morphology is key to preventing lithium filament growth. Reducing pores and increasing grain boundaries in garnet electrolytes enhances stability and performance for safer energy storage.

Keywords:
LLZOcritical current densityinterfacelithium filamentmicrostructure

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Storage

Background:

  • Solid-state lithium batteries offer advanced energy storage potential.
  • Lithium filament formation in solid electrolytes is a major obstacle to their widespread adoption.

Purpose of the Study:

  • To investigate how the morphology of garnet-type solid electrolytes affects their resistance to lithium filament penetration.
  • To develop and validate a novel method for assessing electrolyte resistance to lithium filaments.

Main Methods:

  • Cyclic linear sweep voltammetry was employed to evaluate electrolyte resistance against lithium filaments.
  • Kelvin probe force microscopy and finite element method simulations were used to analyze the influence of microstructure on ion transport.

Main Results:

  • A strong correlation was observed between solid electrolyte morphology and resistance to lithium filament formation.
  • Electrolytes with minimized pores and numerous grain boundaries exhibited superior performance, reaching a critical current density of 3.2 mA cm-2.
  • Enhanced long-term cycling stability was achieved with optimized morphology.

Conclusions:

  • Minimizing pores and creating a uniform morphology with small grains and abundant grain boundaries are crucial for inhibiting lithium penetration.
  • Controlling microstructure is essential for developing robust and safe solid-state lithium batteries.