Colorful 3D Printing: A Critical Feasibility Analysis of Multi-Wavelength Additive Manufacturing

Employing two colors of light to 3D print objects holds potential for accessing advanced printing modes, such as the generation of multi-material objects from a single print. Thus, dual-wavelength-driven photoreactive systems (reactions that require or utilize two wavelengths) and their exploitation as chemo-technological solutions for additive manufacturing technologies have experienced considerable development over the last few years. Such systems saw an increase in printing speeds, a decrease in resolution thresholds, and─perhaps most importantly─the actual generation of multi-material objects. However, the pace at which such reactive systems are developed is moderate and varies significantly depending on the fashion in which the two colors of light are employed. Herein, we address for the first time the varying logic conjugations of light-activated chemical compounds in dual-wavelength photochemical processes in a systematic manner and consider their implications from a photochemical point of view. To date, four dual-wavelength reaction types have been reported, termed synergistic (λ₁ AND λ₂), antagonistic (reversed λ₁ AND λ₂), orthogonal (λ₁ OR λ₂), and─most recently─cooperative (λ₁ AND λ₂ or λ₁ OR λ₂). The progress of their implementation in additive manufacturing is assessed individually, and their concurrent and individual chemical challenges are identified. These challenges need to be addressed for future dual-wavelength photochemical systems to progress multi-wavelength additive manufacturing technologies beyond their current limitations.