Defect Engineering of 2D Copper Tin Composite Nanosheets Realizing Promoted Electrosynthesis Performance of Hydrogen...

The transformation of the two-electron oxygen reduction reaction (2e-ORR) to produce hydrogen peroxide (H₂ O₂ ) is a promising green synthesis approach that can replace the high-energy consumption anthraquinone process. However, designing and fabricating low-cost, non-precious metal electrocatalysts for 2e-ORR remains a challenge. In this study, a method of combining complexation precipitation and thermal treatment to synthesize 2D copper-tin composite nanosheets to serve as the 2e-ORR electrocatalysts is utilized, achieving a high H₂ O₂ selectivity of 92.8% in 0.1 m KOH, and a bulk H₂ O₂ electrosynthesis yield of 1436 mmol·g_cat ^-1 ·h^-1 using a flow cell device. Remarkably, the H₂ O₂ selectivity of this catalyst decreases by only 0.5% after 10,000 cyclic voltammetry (CV) cycles. In addition, it demonstrates that the same catalyst can achieve 97% removal of the organic pollutant methyl blue in an aqueous system solution within 1 h using the on-site degradation technology. A reasonable control of defect concentration on the 2D copper-tin composite nanosheets that can effectively improve the electrocatalytic performance is found. Density functional theory calculations confirm that the surface of the 2D copper-tin composite nanosheets is conducive to the adsorption of the key intermediate OOH^* , highlighting its excellent electrocatalytic performance for ORR with high H₂ O₂ selectivity.