Synthesis of Autofluorescent Phenanthrene Microparticles via Emulsification: A Useful Synthetic Mimic for Polycyclic...

Phenanthrene is the simplest example of a polycyclic aromatic hydrocarbon (PAH). Herein, we exploit its relatively low melting point (101 °C) to prepare microparticles from molten phenanthrene droplets by conducting high-shear homogenization in a 3:1 water/ethylene glycol mixture at 105 °C using poly(N-vinylpyrrolidone) as a non-ionic polymeric emulsifier. Scanning electron microscopy studies confirm that this protocol produces polydisperse phenanthrene microparticles with a spherical morphology: laser diffraction studies indicate a volume-average diameter of 25 ± 21 μm. Such projectiles are fired into an aluminum foil target at 1.87 km s^-1 using a two-stage light gas gun. Interestingly, the autofluorescence exhibited by phenanthrene aids analysis of the resulting impact craters. More specifically, it enables assessment of the spatial distribution of any surviving phenanthrene in the vicinity of each crater. Furthermore, these phenanthrene microparticles can be coated with an ultrathin overlayer of polypyrrole, which reduces their autofluorescence. In principle, such core-shell microparticles should be useful for assessing the extent of thermal ablation that is likely to occur when they are fired into aerogel targets. Accordingly, polypyrrole-coated microparticles were fired into an aerogel target at 2.07 km s^-1. Intact microparticles were identified at the end of carrot tracks and their relatively weak autofluorescence suggests that thermal ablation during aerogel capture did not completely remove the polypyrrole overlayer. Thus, these new core-shell microparticles appear to be useful model projectiles for assessing the extent of thermal processing that can occur in such experiments, which have implications for the capture of intact PAH-based dust grains originating from cometary tails or from plumes emanating from icy satellites (e.g., Enceladus) in future space missions.