A cucurbit[6]uril-based carbon dot for recognizing metal ions and anions in solutions
XingYue Yuan1, ZhiChao Yu1, JianHang Hu1
1Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Institute of Applied Chemistry, Guizhou University, Guiyang 550025, China.
Abstract:
In this paper, fluorescent nitrogen doped carbon quantum dots (CQDs) were synthesized by a hydrothermal method using cucurbit[6]uril (Q[6]) and mandelic acid (MA). Compared with other carbon quantum dots, cucurbit[6]uril has the advantage that its original rigid macrocyclic skeleton was completely retained during the synthesis process. In addition, the performance of the Q[6]-CQDs were characterized by fluorescence and NMR spectroscopies, then the crystal structure of Q[6]-MA-[CdCl4]2- was determined by the single crystal X-ray crystallography. The Q[6]-CQDs showed good water solubility and stable optical property. Subsequently, using the obtained Q[6]-CQDs, a universal fluorescent probe for detecting and recognizing Fe3+, Ba2+, Al3+, I- and ClO- has been developed based on macrocyclic chemistry. Under ideal conditions, the detection limits were calculated to be 3.89 × 10-6 M, 2.58 × 10-5 M, 1.42 × 10-5 M, 6.84 × 10-6 M and 1.50 × 10-5 M.
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