Synthesis and performance analysis of zeolitic imidazolate frameworks for CO₂ sensing applications

In this paper, we investigate the potential use of Zeolitic Imidazolate Frameworks (ZIF-8) as a sensing material for CO₂ detection. Three synthesis techniques are considered for the preparation of ZIF-8, namely room temperature, microwave-assisted, and ball milling. The latter is a green and facile alternative for synthesis with its solvent-free, room-temperature operation. In addition, ball milling produces ZIF-8 samples with superior CO2 adsorption and detection characteristics, as concluded from fluorescence measurements. Characterization tests including X-ray diffraction (XRD), Fourier transform infrared (FTIR), Thermogravimetric analysis (TGA), Field emission scanning electron microscopy (FE-SEM) and Energy-dispersive X-ray spectroscopy (EDS) are conducted to inspect the structural morphology, the thermal stability, and elements content of the ZIF-8 samples obtained from the different aforementioned synthesis techniques. The characterization tests revealed the appearance of a new phase of ZIF-8 which is ZIF-L when deploying the ball milling technique with different structure, morphology, response to CO₂ exposure and thermal stability when compared to its counterparts. Fluorescence measurements are carried out to evaluate the limit of detection (LOD), selectivity, and recyclability of the different ZIF-8 samples. The LOD of the ZIF-8 sample synthesized based on ball milling synthesis technique is 815.2 ppm, while LODs of the samples obtained from microwave and room temperature-based synthesis techniques are 1780.6 ppm and 723.8 ppm, respectively. This indicates that the room temperature and ball milling produced MOFs have comparable LODs. However, the room temperature procedure requires the use of a harmful solvent. The range of LOD demonstrates the suitable use of ZIF-8 for indoor air quality monitoring and other industrial applications.