Sunlight mediated removal of toxic pollutants from Yamuna wastewater using efficient nano TeO₂-ZnO nanocomposites

We have utilised our TeO₂-ZnO nanocomposites for Yamuna wastewater treatment in natural sunlight wherein the sampling site was Nigam Bodh Ghat, Kashmere Gate, Delhi. In BET isotherm, TZ NCs exhibited type IV isotherm forming a H3 like hysteric loop sustaining mesoporous characteristic with an increase in surface area, pore volume and pore diameter of 56.76 m²/g, 0.257 cc/g and 17.18 nm respectively, when compared to pristine ZnO NPs. Yamuna wastewater treatment was carried out using various concentrations of TZ NCs (range 0.1-0.3 g/500 mL) under natural sunlight. Post-treatment, all the physicochemical parameters such as DO, BOD, COD, Nitrates, Ammonia and Phenolic contents were found to be reduced to 10 times bringing Yamuna water parameters within safe limits. Our TZ NCs have shown to have high selectivity for the removal of Chromium from water. Out of all the three concentrations 0.2 g/500 mL or 0.4 mg/mL is the most optimum concentration of TZ NCs for complete Yamuna wastewater treatment. Also, the bacterial culture present in Yamuna water was killed by 90% using TZ having MIC of 0.1 mg/mL. The antibiofilm activity of TZ against K.pneumoniae MTCC 109 was also checked using Congo Red Agar Assay. The presence of heavy metals, their corresponding degradation and leaching studies were analysed using ICP-OES. TZ NCs showed a very minimal leaching rate of Zinc into the water, proving no toxicity associated with these nanocomposites. Further, to observe the safe disposal of TZ NCs into the soil, TZ NCs were utilised for ecotoxicity studies.