XPS and HR TEM Elucidation of the Diversity of Titania-Supported Single-Site Ir Catalyst Performance in
Anna V Nartova1, Ren I Kvon1, Larisa M Kovtunova1
1Department of Physical-Chemical Methods of Investigation, Boreskov Institute of Catalysis SB RAS, Lavrentiev Ave. 5, 630090 Novosibirsk, Russia.
Abstract:
Immobilized [Ir(COD)Cl]2-Linker/TiO2 catalysts with linkers containing Py, P(Ph)2 and N(CH3)2 functional groups were prepared. The catalysts were tested via propene hydrogenation with parahydrogen in a temperature range from 40 °C to 120 °C which was monitored via NMR. The catalytic behavior of [Ir(COD)Cl]2-Linker/TiO2 is explained on the basis of quantitative and qualitative XPS data analysis performed for the catalysts before and after the reaction at 120 °C. It is shown that the temperature dependence of propene conversion and the enhancement of the NMR signal are explained via a combination of the stabilities of both the linker and immobilized [Ir(COD)Cl]2 complex. It is demonstrated that the N(CH3)2-linker is the most stable at the surface of TiO2 under used reaction conditions. As a result, only this sample shows a rise in the enhancement of the NMR signal in the 100-120 °C temperature range.
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