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Recent Progress on Phase Engineering of Nanomaterials.

Qinbai Yun1,2, Yiyao Ge3, Zhenyu Shi1

  • 1Department of Chemistry, City University of Hong Kong, Kowloon, Hong Kong, China.

Chemical Reviews
|November 14, 2023
PubMed
Summary

Phase engineering of nanomaterials (PEN) enables synthesis of materials with unique crystal structures for enhanced properties. This review covers strategies, applications, and future directions in PEN research.

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Solid-State Chemistry

Background:

  • Material properties are dictated by atomic arrangement (phase).
  • Traditionally, nanomaterials adopt stable bulk phases.
  • Nanotechnology allows synthesis of unconventional or amorphous phases.

Purpose of the Study:

  • To review progress in phase engineering of nanomaterials (PEN).
  • To cover synthesis strategies and phase transformation control.
  • To highlight the impact of phase on nanomaterial properties and applications.

Main Methods:

  • Direct synthesis of unconventional phases.
  • Modulation of phase transformation.
  • Diverse synthesis techniques including wet-chemical reduction, CVD, and irradiation.

Main Results:

  • Successful synthesis of unconventional phases in various nanomaterials (metals, oxides, TMDs).
  • Demonstrated influence of phase on catalysis, energy storage, optoelectronics, and sensing.
  • Established PEN as a method to tailor material properties.

Conclusions:

  • PEN offers a powerful approach to design nanomaterials with desired functions.
  • Further research is needed to address challenges and explore new applications.
  • Phase engineering is crucial for advancing nanotechnology.